Practicing Success

Target Exam

CUET

Subject

Chemistry

Chapter

Physical: Chemical Kinetics

Question:

What are the factors that determine an effective collision?

Options:

Translational collision and energy of activation

Threshold energy and proper orientation

Proper orientation and steric bulk of the molecule

Collision frequency, threshold energy, and proper orientation

Correct Answer:

Collision frequency, threshold energy, and proper orientation

Explanation:

The correct answer is option 4. Collision frequency, threshold energy, and proper orientation.

Let us delve into each factor that determines an effective collision in chemical reactions:

Collision Frequency: Chemical reactions require reactant molecules to collide with each other. The more frequently collisions occur between reactant molecules, the greater the chances of a reaction taking place. Collision frequency is influenced by factors such as the concentration of reactants and the temperature of the system. Higher concentrations of reactants lead to more frequent collisions because there are more reactant molecules per unit volume, increasing the likelihood of collisions. Increased temperature also increases collision frequency because molecules move faster and collide more frequently.

Threshold Energy (Activation Energy):

Even if reactant molecules collide, not all collisions result in a chemical reaction. For a reaction to occur, the colliding molecules must possess a minimum amount of energy called the activation energy. Activation energy is the energy barrier that must be overcome for reactant molecules to transform into products. It represents the minimum energy required to initiate a chemical reaction by breaking existing bonds and forming new ones. Collisions between molecules that do not possess sufficient energy to overcome the activation energy barrier result in ineffective collisions—they do not lead to product formation.

Proper Orientation:

In addition to having sufficient energy, reactant molecules must collide in a specific orientation relative to each other for the reaction to proceed effectively. This means that the reacting atoms or groups within the molecules must come into contact in a way that allows the necessary bonds to be broken and new bonds to form. Proper orientation ensures that the reactive parts of the molecules are aligned correctly during collision, facilitating the transition from reactants to products.

In summary, an effective collision in chemical reactions requires:

High collision frequency: Ensures that reactant molecules come into contact with each other frequently.

Sufficient activation energy: Allows the molecules to overcome the energy barrier required to initiate the reaction.

Proper orientation: Ensures that the reactive parts of the molecules align correctly during collision, facilitating the formation of products.

These factors collectively determine whether a collision between reactant molecules will result in a successful chemical reaction, leading to the formation of products. Therefore, they are crucial considerations in understanding reaction kinetics and the factors that influence reaction rates.