Practicing Success

Target Exam

CUET

Subject

Chemistry

Chapter

Organic: Aldehydes, Ketones and Carboxylic Acids

Question:

What is the correct order of pKvalues of the following acids?

Options:

Benzoic acid > m-Nitrobenzoic acid > p-Nitrobenzoic acid

Benzoic acid > p-Nitrobenzoic acid > m-Nitrobenzoic acid

p-Nitrobenzoic acid > m-Nitrobenzoic acid > Benzoic acid

m-Nitrobenzoic acid > p-Nitrobenzoic acid > Benzoic acid

Correct Answer:

Benzoic acid > m-Nitrobenzoic acid > p-Nitrobenzoic acid

Explanation:

Nitro group is electron withdrawing in nature and increases the acidic strength of acids. The electron withdrawing effect of NO2 is pronounced at para position more than meta position, hence the p-isomer is more acidic and has a lower pKa value than m-isomer.