The half-life of a first order reaction:
(A) depends on the reactant concentration raised to the first power
(B) depends on rate constant
(C) is independent of the reactant concentration
(D) is independent of rate constant
Choose the correct answer from the options given below:
Answer & explanation
Correct answer: option 2
The correct answer is Option (2) → B, C
For a first order reaction, ln([R]0/[R]) = kt. At t = t1/2, [R] = [R]0/2:
t1/2 = 2.303 log 2 / k = 0.693/k
(A) depends on the reactant concentration raised to the first power — False. [R]0 does not appear in t1/2 = 0.693/k (that is true of a zero order reaction).
(B) depends on rate constant — True. t1/2 is inversely proportional to k.
(C) is independent of the reactant concentration — True. The half-life is the same whatever the starting concentration.
(D) is independent of rate constant — False. It contradicts t1/2 = 0.693/k.
NCERT (2026-27 edition):
Half-Life of a Reaction – “… t1/2 = 0.693/k (3.17)
It can be seen that for a first order reaction, half-life period is constant, i.e., it is independent of initial concentration of the reacting species. The half-life of a first order equation is readily calculated from the rate constant and vice versa.”