Practicing Success
For a reaction \(A\text{ + }B \longrightarrow C\text{ + }D\) if the concentration of A is doubled without altering the concentration of B, the rate gets doubled. If the concentration of B is increased by nine times without altering the concentration of A, the rate gets tripled. The order of the reaction is: |
2 1 \(\frac{3}{2}\) \(\frac{4}{3}\) |
\(\frac{3}{2}\) |
The correct answer is option 3. \(\frac{3}{2}\). The given reaction is \(A\text{ + }B \longrightarrow C\text{ + }D\) So, \(r = k [A]^{\alpha} [B]^{\beta}\) -------(1) \(2r = k [2A]^{\alpha} [B]^{\beta}\) -------(2) \(3r = k [A]^{\alpha} [9B]^{\beta}\) -------(3) Dividing equation (3) by (1),we get \(3 = 9^{\beta}\) or, \(3^1 = 3^{2 \beta}\) or, \(2 \beta = 1\) or, \(\beta = \frac{1}{2}\) Dividing equation (2) by (1),we get \(2 = 2^{\alpha }\) or, \(2^1 = 2^{\alpha }\) or, \(\alpha = 1\) So, the order of the reaction will be \(\alpha + \beta = 1 + \frac{1}{2} = \frac{3}{2}\) |