An organic compound 'A' with molecular formula CH4O reacts with HI to give an alkyl iodide which than reacts with potassium cyanide to produce 'B'. Compound 'B' on reduction followed by reaction with HNO2 gives an alcohol which on oxidation gives 'C'. Compound 'C' on oxidation followed by reaction with CH3MgBr gives 'D' which on hydrolysis gives compound 'E' which is also an alcohol. |
What is the name of the compound 'E'? |
1-Propanol 2-Propanol tert-butanol Butan-2-ol |
2-Propanol |
The correct answer is option 2. 2-Propanol.
Remember Aldehyde + Grignard → secondary alcohol Ketone + Grignard → tertiary alcohol Step 1: Identify A (CH₄O) CH₃OH + HI → CH₃I (methyl iodide) Step 2: Formation of B Step 3: Reduction of B Step 4: Reaction with HNO₂ CH₃CH₂NH₂ → CH₃CH₂OH (ethanol) Step 5: Oxidation to C Step 6: Reaction with CH₃MgBr Gives: CH₃–CHOH–CH₃ Final compound E:
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