Butanone is less reactive than propanal towards nucleophilic addition reaction because: |
more \(+I\) effect found in butanone less \(+I\) effect found in butanone more \(+I\) effect found in propanal less \(+ve\) charge found on carbonyl group of propanal |
more \(+I\) effect found in butanone |
The correct answer is option 1. more \(+I\) effect found in butanone. In butanone (\(CH_3-CO-CH_2-CH_3\)), the two methyl (\(CH_3\)) groups attached to the carbonyl carbon can exert a \(+I\) effect, donating electron density towards the carbonyl carbon. This donation of electrons by the methyl groups would indeed decrease the electrophilicity of the carbonyl carbon in butanone. Meanwhile, in propanal (\(CH_3-CH_2-CHO\)), there is only one methyl group attached to the carbonyl carbon. Therefore, the \(+I\) effect from the methyl group in propanal is less pronounced compared to the two methyl groups in butanone. Thus, the increased \(+I\) effect from the two methyl groups in butanone compared to the single methyl group in propanal would indeed lead to a decrease in the electrophilicity of the carbonyl carbon in butanone, making butanone less reactive towards nucleophilic addition reactions. Therefore, option 1. more \(+I\) effect found in butanone is the correct answer. |