Practicing Success

Target Exam

CUET

Subject

Chemistry

Chapter

Organic: Haloalkanes and Haloarenes

Question:

What is the hybridisation of carbon in diamond?

Options:

sp

sp2

sp3

sp3d

Correct Answer:

sp3

Explanation:

The hybridization of carbon in diamond is 3. sp3.

In sp3 hybridization, one s orbital and three p orbitals combine to form four equivalent sp3 hybrid orbitals. These orbitals are arranged tetrahedrally around the carbon atom. In diamond, each carbon atom is bonded to four other carbon atoms by single covalent bonds. The sp3 hybrid orbitals on each carbon atom overlap with the sp3 hybrid orbitals on the other four carbon atoms to form these bonds.

The sp2 hybridization has three equivalent sp2 hybrid orbitals and one p orbital. The sp2 hybrid orbitals are arranged in a trigonal planar configuration. In graphite, each carbon atom is bonded to three other carbon atoms by single covalent bonds. The sp2 hybrid orbitals on each carbon atom overlap with the sp2 hybrid orbitals on the other three carbon atoms to form these bonds. The p orbital on each carbon atom overlaps with a p orbital on an adjacent carbon atom to form a pi bond.

The sp hybridization has one sp hybrid orbital and one p orbital. The sp hybrid orbital is linear. In acetylene, each carbon atom is bonded to one other carbon atom by a triple bond. The sp hybrid orbital on each carbon atom overlaps with the sp hybrid orbital on the other carbon atom to form a sigma bond. The p orbitals on each carbon atom overlap to form two pi bonds.

The sp3d hybridization has four sp3d hybrid orbitals and one d orbital. The sp3d hybrid orbitals are arranged in a trigonal bi-pyramidal configuration. This hybridization is rarely seen in carbon compounds.

Therefore, the hybridization of carbon in diamonds is sp3.