What is the ratio of the frequencies of the long wavelength limits of Lyman and Balmer series of hydrogen spectrum? |
27 : 5 4 : 1 5 : 27 1 : 4 |
5 : 27 |
The correct answer is Option (1) → 5 : 27 According to Rydberg formula, $\frac{1}{λ}=R_H\left(\frac{1}{n_f^2}-\frac{1}{n_i^2}\right)$ for longest $λ$ of lyman series, $(n_f=1,n_i=2)$ $\frac{1}{λ_1}=R_H\left(\frac{1}{1^2}-\frac{1}{4}\right)$ $⇒λ_1=\frac{4}{3R_H}$ for longest $λ$ of Balmer series, $(n_f=2,n_i=3)$ $⇒\frac{1}{λ_2}=R_H\left(\frac{1}{2^2}-\frac{1}{3^2}\right)$ $⇒λ_2=\frac{36}{5R_H}$ $∴\frac{λ_1}{λ_2}=\frac{4}{3R_H}×\frac{5R_H}{36}=\frac{5}{27}$ |