The unit of rate constant of a reaction with the rate law, Rate = $k[A]^{3/2}[B]^{-1}$ is |
$s^{-1}$ $mol\, L^{-1}\, s^{-1}$ $L^{1/2}\, mol^{-1/2}\, s^{-1}$ $mol^{1/2}\, L^{-1/2}\, s^{-1}$ |
$mol^{1/2}\, L^{-1/2}\, s^{-1}$ |
The correct answer is Option (4) → $mol^{1/2}\, L^{-1/2}\, s^{-1}$ We need to calculate the unit of rate constant k step by step. Given rate law: $\text{Rate} = k [A]^{3/2} [B]^{-1}$
Step 1: Express units $\text{mol L}^{-1} \text{s}^{-1} = k \times (\text{mol L}^{-1})^{3/2} \times (\text{mol L}^{-1})^{-1}$ $\text{mol L}^{-1} \text{s}^{-1} = k \times (\text{mol}^{3/2} \text{L}^{-3/2}) \times (\text{mol}^{-1} \text{L}^{1})$ $\text{mol L}^{-1} \text{s}^{-1} = k \times (\text{mol}^{3/2 - 1} \text{L}^{-3/2 + 1})$ $\text{mol L}^{-1} \text{s}^{-1} = k \times (\text{mol}^{1/2} \text{L}^{-1/2})$ Step 2: Solve for k $k = \frac{\text{mol L}^{-1} \text{s}^{-1}}{\text{mol}^{1/2} \text{L}^{-1/2}} = \text{mol}^{1 - 1/2} \text{L}^{-1 + 1/2} \text{s}^{-1}$ $k = \text{mol}^{1/2} \text{L}^{-1/2} \text{s}^{-1}$ |