The Nernst equation corresponding to the cell reaction given below, is $ \text{Ni}(\text{s})+2\text{Ag}^{+}(\text{aq})\rightarrow\text{Ni}^{2+}(\text{aq})+2\text{Ag}(\text{s}) $ |
$E_{\text{cell}}=E_{\text{cell}}^{\circ}-\frac{RT}{2F}\ln\frac{[\text{Ni}^{2+}]}{[\text{Ag}^{+}]^2}$ $ E_{\text{cell}}=E_{\text{cell}}^{\circ}-\frac{RT}{2F}\log\frac{[\text{Ni}^{2+}]}{[\text{Ag}^{+}]^2} $ $ E_{\text{cell}}=E_{\text{cell}}^{\circ}-\frac{RT}{2F}\ln\frac{[\text{Ni}^{2+}]}{2[\text{Ag}^{+}]^2} $ $ E_{\text{cell}}=E_{\text{cell}}^{\circ}-\frac{RT}{F}\ln\frac{[\text{Ni}^{2+}][\text{Ag}]^2}{[\text{Ag}^{+}]^2[\text{Ni}]} $ |
$E_{\text{cell}}=E_{\text{cell}}^{\circ}-\frac{RT}{2F}\ln\frac{[\text{Ni}^{2+}]}{[\text{Ag}^{+}]^2}$ |
The correct answer is Option (1) → $E_{\text{cell}}=E_{\text{cell}}^{\circ}-\frac{RT}{2F}\ln\frac{[\text{Ni}^{2+}]}{[\text{Ag}^{+}]^2}$ For any electrode reaction, $ \text{M}^{n+}(\text{aq})+n\text{e}^{-}\rightarrow\text{M}(\text{s}) $ According to Nernst equation, The electrode potential at any concentration measured with respect to standard hydrogen electrode can be represented by: $ E_{(\text{M}^{n+}/\text{M})}=E_{(\text{M}^{n+}/\text{M})}^{\circ}-\frac{RT}{nF}\ln\frac{[\text{M}]}{[\text{M}^{n+}]} $ but concentration of solid M is taken as unity The cell reaction is: $ \text{Ni}(\text{s})+2\text{Ag}^{+}(\text{aq})\rightarrow\text{Ni}^{2+}(\text{aq})+2\text{Ag}(\text{s}) $ The Nernst equation can be written as $ E_{(\text{cell})}=E_{(\text{cell})}^{\circ}-\frac{RT}{2F}\ln\frac{[\text{Ni}^{2+}]}{[\text{Ag}^{+}]^2} $ |