The synthesis of alkyl fluoride is best accomplished by the following reaction

\(CH_3Br + AgF \longrightarrow CH_3F + AgBr\)

The reaction is termed as:

Swart’s reaction

The correct answer is option 1. Swart’s reaction.

Swart's reaction is a chemical reaction that involves the conversion of an alkyl halide, in this case, methyl bromide (\(CH_3Br\)), into an alkyl fluoride (\(CH_3F\)) using silver fluoride (\(AgF\)). The reaction can be represented as:

\(CH_3Br + AgF \longrightarrow CH_3F + AgBr\)

Here is a detailed explanation of the reaction:

Starting Materials:

Methyl Bromide (\(CH_3Br\)):  This is an alkyl halide, which means it contains a carbon atom bonded to a halogen atom (bromine, Br). In Swart's reaction, this compound serves as the source of the alkyl group (the \(CH_3\) part) that will be transferred to the fluoride ion.

Silver Fluoride (\(AgF\)):  This is the key reagent in the reaction. It contains a silver cation (\(Ag^+\)) and a fluoride anion (\(F^-\)). The silver cation is critical for facilitating the substitution reaction.

Reaction Mechanism:

The Swart's reaction is a substitution reaction, specifically a nucleophilic substitution reaction. Here's how it proceeds:

The silver fluoride (\(AgF\)) dissociates in solution to form silver cations (\(Ag^+\)) and fluoride anions (\(F^-\)):

\(AgF \longrightarrow Ag^+ + F^-\)

The fluoride ion (\(F^-\)) acts as a nucleophile. It is attracted to the electrophilic carbon atom in methyl bromide (\(CH_3Br\)). This carbon atom is electrophilic because it is partially positive due to the presence of the electronegative bromine atom.

The fluoride ion (\(F^-\)) attacks the carbon atom in methyl bromide (\(CH_3Br\)), resulting in the displacement of the bromine atom:

\(CH_3Br + F^- \longrightarrow CH_3F + Br^-\)

The reaction results in the formation of methyl fluoride (\(CH_3F\)), which is the desired product, and bromide ions (\(Br^-\)). Additionally, the silver cations (\(Ag^+\)) that were formed initially combine with the bromide ions (\(Br^-\)) to form insoluble silver bromide (\(AgBr\)). This forms a precipitate that can be easily separated from the reaction mixture.

Outcome:

The primary outcome of Swart's reaction is the conversion of the alkyl halide (\(CH_3Br\)) into the corresponding alkyl fluoride (\(CH_3F\)), and the formation of silver bromide (\(AgBr\)) as a byproduct.
This reaction is valuable because it allows chemists to selectively prepare alkyl fluorides, which can be challenging to synthesize using other methods due to the high reactivity of fluorine. Alkyl fluorides are important compounds in various chemical and pharmaceutical industries, making Swart's reaction a useful synthetic tool.