Target Exam

CUET

Subject

Chemistry

Chapter

Organic: Haloalkanes and Haloarenes

Question:

The C-Br bond in bromobenzene as compared with C-Br bond in ethyl bromide is

Options:

Longer and weaker

Shorter and weaker

Shorter and stronger

Longer and stronger

Correct Answer:

Shorter and stronger

Explanation:

The correct answer is Option (3) → Shorter and stronger

In bromobenzene, the C–Br bond has partial double bond character due to resonance between the bromine lone pair and the benzene ring. This makes the bond:

  • Shorter than a normal C–Br single bond
  • Stronger than the C–Br bond in alkyl halides

In ethyl bromide, the C–Br bond is a normal single (σ) bond, so it is longer and weaker.