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In aldehydes, the carbonyl group is bonded to a carbon and hydrogen, while in ketones it is bonded to two carbon atoms. The carbonyl group is bonded to oxygen are known as carboxylic acid and their derivatives. |
1,3-Diphenylprop-2-en-1-one is produced by the following |
\(C_6H_5CHO\) and \(C_6H_5COCH_3\): Cross aldol condensation \(C_6H_5COOH\) and \(C_6H_5COCH_3\): Cross aldol condensation \(C_6H_5CHO\) : Self condensation \(C_6H_5COCH_3\): Self condensation |
\(C_6H_5CHO\) and \(C_6H_5COCH_3\): Cross aldol condensation |
The correct answer is option 1. \(C_6H_5CHO\) and \(C_6H_5COCH_3\): Cross aldol condensation. Out of the given options, the correct reaction for the production of 1,3-diphenylprop-2-en-1-one is \(C_6H_5CHO\) and \(C_6H_5COCH_3\): Cross aldol condensation. Here's why: Neither benzaldehyde \((C_6H_5CHO)\) nor acetophenone \((C_6H_5COCH_3)\) can undergo self-condensation to form 1,3-diphenylprop-2-en-1-one. Self-condensation of benzaldehyde would lead to benzoin \((C_6H_5CH(OH)CH(OH)C_6H_5)\), and self-condensation of acetophenone wouldn't yield any α-hydrogens for aldol condensation. The reaction between benzaldehyde and acetophenone is a classic example of cross-aldol condensation. The enolate formed from acetophenone acts as the nucleophile, attacking the electrophilic carbonyl carbon of benzaldehyde. Subsequent dehydration of the aldol product leads to the formation of 1,3-diphenylprop-2-en-1-one. Mechanism: |