Practicing Success

Target Exam

CUET

Subject

Chemistry

Chapter

Physical: Solutions

Question:

Liquid A and B form an ideal solution at 30oC. At this temperature, vapour pressure of pure A and pure B is 200 mm Hg and 50 mm Hg respectively. What is the vapour pressure of the solution if Equal weight of A and B is added? (Given: Molecular mass of A and B are 40 and 60 respectively) 

Options:

120 mm Hg

130 mm Hg

140 mm Hg

150 mm Hg

Correct Answer:

140 mm Hg

Explanation:

nA = \(\frac{x}{40}\) , nB = \(\frac{x}{60}\)

ΧA = \(\frac{nA}{nA + nB}\) = \(\frac{x/40}{x/40 + x/60}\) = 0.6

and XB = 1 - 0.6 = 0.4

PT = PA + PB = PoAXA + PoBXB = 200 x 0.6 + 50 x 0.4 = 120 + 20 = 140 mm Hg