List of Ligands are given below from spectrochemical series, rearrange in the order of increasing field strength: A. \(SCN^-\) B. \(Cl^-\) C. \(F^-\) D. \(OH^-\) E. \(CN^-\) Choose the answer from the options given below: |
D < A < B < C < E B < A < C < D < E A < B < C < D < E A < C < D < E < B |
A < B < C < D < E |
The correct answer is option 3. A < B < C < D < E. The spectrochemical series is a ranking of ligands based on their ability to cause splitting of d-orbitals in transition metal complexes. This series helps predict the extent of the d-orbital splitting, which in turn influences the colors and magnetic properties of these complexes. The series typically progresses from weak-field ligands to strong-field ligands. Weak-field ligands cause small energy differences between the d orbitals, leading to low splitting, while strong-field ligands cause larger energy differences and greater splitting. Here's a simplified version of the spectrochemical series, arranged from weak to strong field ligands: \(I^− < Br^− < S^{2−} < SCN^− < Cl^− < NO_3^− < N_3^− < F^− < OH^− < C_2O_4^{2−} < H_2O < NCS^− < CH_3CN < py < NH_3 < en < bipy < phen < NO_2^− < PPh_3 < CN^− < CO\) This order helps in understanding the electronic structure and properties of transition metal complexes. For example, complexes formed with strong-field ligands tend to have lower spin states, making them less likely to be paramagnetic and often exhibiting different colors compared to complexes formed with weak-field ligands. |