Target Exam

CUET

Subject

Chemistry

Chapter

Physical: Electro Chemistry

Question:

The standard reduction potential of $Ag^+/Ag$ electrode is +0.80 V. Choose the correct statement based on this information.

Options:

$Ag^+/Ag$ couple is a stronger reducing agent than $H^+/H_2$ couple

$Ag^+/Ag$ couple is a weaker reducing agent than $H^+/H_2$ couple

$Ag$ can be easily oxidised as compared to $H_2$

$Ag^+/Ag$ will act as anode when coupled with Standard Hydrogen electrode to form a cell

Correct Answer:

$Ag^+/Ag$ couple is a weaker reducing agent than $H^+/H_2$ couple

Explanation:

The correct answer is Option (2) → $Ag^+/Ag$ couple is a weaker reducing agent than $H^+/H_2$ couple

The standard reduction potential of the Ag⁺/Ag couple is +0.80 V, which is greater than that of the standard hydrogen electrode (SHE = 0.00 V).

Key implications:

  • Higher $E^\circ$ ⇒ greater tendency to be reduced
  • Therefore, Ag⁺ is reduced more easily than H⁺
  • Consequently, Ag (metal) is less easily oxidised than H₂
  • Hence, Ag is a weaker reducing agent than H₂

Now check the statements:

  • Ag⁺/Ag couple is a stronger reducing agent than H⁺/H₂ couple  -- Incorrect
  • Ag⁺/Ag couple is a weaker reducing agent than H⁺/H₂ couple --correct
  • Ag can be easily oxidised as compared to H₂--  incorrect
  • Ag⁺/Ag will act as anode when coupled with SHE--  incorrect