Half life of the zero order reaction is:
Answer & explanation
Correct answer: option 4
The correct answer is Option (4) → Directly proportional to initial concentration of the reactant
The half-life of a reaction is the time in which the concentration of a reactant is reduced to one half of its initial concentration.
For a zero-order reaction, rate constant is given by equation
$ k=\frac{[\text{R}]_0-[\text{R}]}{t} $
At
$ t=t_{\frac12} $
, and
$ [\text{R}]=\frac12[\text{R}]_0 $
The rate constant at half life becomes
$ k=\frac{[\text{R}]_0-1/2[\text{R}]_0}{t_{1/2}} $
$ t_{1/2}=\frac{[\text{R}]_0}{2k} $
It is clear that half life for a zero-order reaction is directly proportional to the initial concentration of the reactants and inversely proportional to the rate constant.