Practicing Success
Which of the following compounds can be distinguished from iodoform test? |
Benzaldehyde and benzophenone Benzaldehyde and formaldehyde Acetophenone and acetaldehyde Acetophenone and benzophenone |
Acetophenone and benzophenone |
The correct answer is option 4. Acetophenone and benzophenone. Iodoform test involves the reaction of a compound with sodium hypoiodite to detect the presence of CH3CO or CH3CH(OH) group. A positive test forms CHI3 (iodoform) in the form of a yellow precipitate. Acetaldehyde and acetophenone give yellow ppt in this test, whereas formaldehyde, benzophenone and benzaldehyde do not undergo this test due to the absence of CH3CO group in their structures. Since Acetophenone gives a positive iodoform test and benzophenone gives negative iodoform so they can be easily distinguished by iodoform test. |