Target Exam

CUET

Subject

Chemistry

Chapter

Organic: Biomolecules

Question:

Gluconic acid is obtained when

Options:

Sucrose is boiled with dil $HCl$ or $H_2SO_4$ in alcoholic solution.

Glucose is treated with a mild oxidizing agent like bromine water.

Upon hydrolysis of starch with dilute $H_2SO_4$ at 393 K under pressure.

Glucose is prolonged heated with hydrogen iodide.

Correct Answer:

Glucose is treated with a mild oxidizing agent like bromine water.

Explanation:

The correct answer is Option (2) → Glucose is treated with a mild oxidizing agent like bromine water.

Gluconic acid is formed by mild oxidation of the aldehyde (–CHO) group of glucose to a carboxylic acid (–COOH) without affecting the –OH groups.

Option 1 Sucrose hydrolysis gives glucose and fructose. No oxidation occurs.

Option 2 Glucose + Br₂ water → Gluconic acid Selective oxidation of –CHO group. Correct.

Option 3 Hydrolysis of starch produces glucose. No oxidation.

Option 4 Heating with HI reduces glucose to n-hexane. No gluconic acid formed.