Practicing Success

Target Exam

CUET

Subject

Chemistry

Chapter

Inorganic: P Block Elements

Question:

Group 15 includes nitrogen, phosphorus, arsenic, antimony, bismuth and moscovium. As we go down the group, there is a shift from non-metallic to metallic through metalloidic character. Nitrogen and phosphorus are non-metals, arsenic and antimony metalloids, bismuth and moscovium are typical metals. Molecular nitrogen comprises 78% by volume of the atmosphere. In the earth’s crust, it occurs as sodium nitrate, NaNO3 (called Chile saltpetre) and potassium nitrate (Indian saltpetre). It is found in the form of proteins in plants and animals. Phosphorus occurs in minerals of the apatite family, Ca9(PO4)6. CaX2 [X = F, Cl or OH] [e.g., fluorapatite Ca9(PO4)6.CaF2] which are the main components of phosphate rocks. Phosphorus is an essential constituent of animal and plant matter. It is present in bones as well as in living cells. Phosphoproteins are present in milk and eggs. Arsenic, antimony and bismuth are found mainly as sulphide minerals. Moscovium is a synthetic radioactive element. Its symbol is Mc, atomic number 115, atomic mass 289 and electronic configuration [Rn] 5f146d107s27p3. Due to very short half life and availability in very little amount, its chemistry is yet to be established.

Which of the following represents the general electronic configuration of an element belonging to the p-block of the periodic table?

Options:

(n-2)f0(n-1)d0ns2 np0–6

(n-2)f0(n-1)d1–10 ns2 np-6

(n-2)f0(n-1)d0 ns2np1-6

(n-2)f1-14(n-1)d1-10ns2np1-6

Correct Answer:

(n-2)f0(n-1)d0 ns2np1-6

Explanation:

The general configuration representation of p-block elements is (n-2)f0(n-1)d0ns2np1-6. This is because the s-subshell is completely filled, whereas, the p-subshell contains at least 1 electron. Other options are ruled out since either or both d – and f – subshell are partially filled.