Target Exam

CUET

Subject

Chemistry

Chapter

Inorganic: D and F Block Elements

Question:

Match List-I with List-II

List-I (Electronic configuration)

List-II (Ion)

(A) $[Ar] 3d^{10}$

(I) $Ce^{4+}$

(B) $[Xe]$

(II) $Cu^+$

(C) $[Rn]$

(III) $Th^{4+}$

(D) $[Xe] 4f^{14} 5d^1$

(IV) $Lu^{2+}$

Choose the correct answer from the options given below:

Options:

(A)-(II), (B)-(I), (C)-(III), (D)-(IV)

(A)-(I), (B)-(III), (C)-(II), (D)-(IV)

(A)-(I), (B)-(II), (C)-(IV), (D)-(III)

(A)-(III), (B)-(IV), (C)-(I), (D)-(II)

Correct Answer:

(A)-(II), (B)-(I), (C)-(III), (D)-(IV)

Explanation:

The correct answer is Option (1) → (A)-(II), (B)-(I), (C)-(III), (D)-(IV)

List-I (Electronic configuration)

List-II (Ion)

(A) $[Ar] 3d^{10}$

(II) $Cu^+$

(B) $[Xe]$

(I) $Ce^{4+}$

(C) $[Rn]$

(III) $Th^{4+}$

(D) $[Xe] 4f^{14} 5d^1$

(IV) $Lu^{2+}$

(A) $[Ar]3d^{10}$ $\rightarrow$ (II) $Cu^+$: Copper ($Z=29$) has a neutral configuration of $[Ar]3d^{10}4s^1$. Removing one electron from the $4s$ orbital to form the $Cu^+$ ion leaves the filled $3d$ subshell.

(B) $[Xe]$ $\rightarrow$ (I) $Ce^{4+}$: Cerium ($Z=58$) has a neutral configuration of $[Xe]4f^1 5d^1 6s^2$. To form the $Ce^{4+}$ ion, all four valence electrons are removed, leaving the stable noble gas configuration of Xenon.

(C) $[Rn]$ $\rightarrow$ (III) $Th^{4+}$: Thorium ($Z=90$) is an actinide with a neutral configuration of $[Rn]6d^2 7s^2$. Losing four electrons results in the noble gas configuration of Radon.

(D) $[Xe]4f^{14}5d^1$ $\rightarrow$ (IV) $Lu^{2+}$: Lutetium ($Z=71$) has a neutral configuration of $[Xe]4f^{14}5d^1 6s^2$. Removing the two $6s$ electrons to form $Lu^{2+}$ leaves the $4f^{14}5d^1$ configuration.