The appropriate adjective clause to complete the sentence is: Option 2: when
Here's why:
- Where indicates a location, not the time. It would be used if you were asking about the place where the train leaves, not the time.
- When modifies the noun "time" and specifies the moment the train leaves. It answers the question "at what time will the train leave?"
- How describes the manner or way something is done. It wouldn't be appropriate for describing the time the train leaves.
- Who refers to a person or thing. It wouldn't be appropriate for describing the time the train leaves.
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