Target Exam

CUET

Subject

Chemistry

Chapter

Inorganic: D and F Block Elements

Question:

What is the correct order of following steps in the preparation of potassium permanganate?

(A) disproportionation in a neutral or acidic solution
(B) production of dark green $K_2MnO_4$
(C) $MnO_2$
(D) fusion with alkali metal hydroxide and $KNO_3$

Choose the correct answer from the options given below:

Options:

(B), (A), (C), (D)

(C), (D), (B), (A)

(A), (B), (D), (C)

(D), (B), (C), (A)

Correct Answer:

(C), (D), (B), (A)

Explanation:

The correct answer is Option (2) → (C), (D), (B), (A)

Preparation of $KMnO_4$ is done from $MnO_2$ in two major stages:

Step 1: Oxidation of $MnO_2$ to manganate $(K_2MnO_4$) by fusion with KOH and an oxidizing agent like $KNO_3$

Step 2: Conversion of manganate into permanganate by disproportionation in acidic or neutral medium

Option 2: (C), (D), (B), (A)

This starts correctly with $MnO_2$ as the raw material.

It is fused with alkali metal hydroxide and $KNO_3$ which oxidizes $MnO_2$.

This produces dark green $K_2MnO_4$.

Finally, manganate undergoes disproportionation in acidic or neutral solution to form $KMnO_4$.

Thus, this is the correct preparation sequence.