What is the correct order of following steps in the preparation of potassium permanganate? (A) disproportionation in a neutral or acidic solution Choose the correct answer from the options given below: |
(B), (A), (C), (D) (C), (D), (B), (A) (A), (B), (D), (C) (D), (B), (C), (A) |
(C), (D), (B), (A) |
The correct answer is Option (2) → (C), (D), (B), (A) Preparation of $KMnO_4$ is done from $MnO_2$ in two major stages: Step 1: Oxidation of $MnO_2$ to manganate $(K_2MnO_4$) by fusion with KOH and an oxidizing agent like $KNO_3$ Step 2: Conversion of manganate into permanganate by disproportionation in acidic or neutral medium Option 2: (C), (D), (B), (A) This starts correctly with $MnO_2$ as the raw material. It is fused with alkali metal hydroxide and $KNO_3$ which oxidizes $MnO_2$. This produces dark green $K_2MnO_4$. Finally, manganate undergoes disproportionation in acidic or neutral solution to form $KMnO_4$. Thus, this is the correct preparation sequence. |