Practicing Success

Target Exam

CUET

Subject

Chemistry

Chapter

Organic: Aldehydes, Ketones and Carboxylic Acids

Question:

Arrange the following compounds in increasing order of their reactivity in nucleophilic addition reactions. (I) Ethanal, (II) Propanal, (III) Propanone, (IV) Butanone.

Options:

(III) < (II) < (I) < (IV)

(II) < (I) < (III) < (IV)

(IV) < (III) < (II) < (I)

(I) < (II) < (III) < (IV)

Correct Answer:

(IV) < (III) < (II) < (I)

Explanation:

Reactivity decreases as the size and number of alkyl groups around C=O bond increases. Thus, reactivity increases in the order: butanone (IV) < propanone (III) < propanal (II) < ethanal(I).