Metaphosphoric acid is:
Answer & explanation
Correct answer: option 3
The correct answer is Option (3) → \((HPO_3)_3\)
Metaphosphoric acid has the empirical formula \( \ce{HPO3} \) and exists only in polymeric forms, (HPO3)n, with phosphorus in the +5 state. Its cyclic trimer, cyclotrimetaphosphoric acid, (HPO3)3, is a ring of three \( \ce{PO4} \) units joined through P–O–P bonds, each P carrying one –OH and one P=O.
Note: This question is from the pre-rationalised NCERT book (2022-23). The topic is not there in the latest NCERT book (2026-27), and it is also out of the CUET 2026 syllabus.
NCERT (Pre-rationalised edition, 2022-23):
Oxoacids of Phosphorus
