What is the oxidation number of the metal of $[\text{Co}(\text{H}_2\text{O})(\text{CN})(\text{ox})_2]^{2-}$ coordination entity? |
+5 +1 +3 +2 |
+3 |
The correct answer is Option (3) → +3 Oxidation state of the central metal is calculated by considering the charges of all ligands and the overall charge of the complex. Neutral ligands contribute 0 charge, while anionic ligands contribute their respective negative charges. Let oxidation state of $\text{Co} = x$ Ligand charges: $\text{H}_2\text{O}$ is neutral $\rightarrow 0$ $\text{CN}^- \rightarrow -1$ Oxalate $(\text{ox}^{2-}) \rightarrow -2$ each Since there are two oxalate ligands: Total ligand charge = $\text{CN}^- = -1$ $2 \times \text{ox}^{2-} = -4$ Total ligand charge $= -5$ Overall charge of complex $= -2$ So, $x + (-5) = -2$ $x = +3$ |