Practicing Success
When two different halogens react with each other, interhalogen compounds are formed. They can be assigned general compositions as XX’ , XX’3, XX’5 and XX’7 where X is halogen of larger size and X’ of smaller size and X is more electropositive than X’. As the ratio between radii of X and X’ increases, the number of atoms per molecule also increases. Thus, iodine (VII) fluoride should have maximum number of atoms as the ratio of radii between I and F should be maximum. That is why its formula is IF7 (having maximum number of atoms). |
Which of the following is true about interhalogen compounds? |
They have unpaired electrons They are highly stable They are diamagnetic They are paramagnetic |
They are diamagnetic |
Interhalogen compounds are diamagnetic in nature. This is because they have bond pairs and lone pairs. The A-X bond in interhalogen compounds is much weaker than the X-X bond in halogens, except for the F-F bond. |