What is the major product of Carbylamine reaction? |
Cyanide Isocyanide Nitrile Alkane |
Isocyanide |
The correct answer is Option (2) → Isocyanide The major product of the Carbylamine reaction is an isocyanide. The Carbylamine reaction (also known as the isocyanide test) is a chemical reaction used to synthesize isocyanides (also called carbylamines). This reaction involves the treatment of a primary amine (RNH₂), chloroform (CHCl₃), and a strong base (like KOH or NaOH) under heating conditions. The general reaction is: \(RNH_2 + CHCl_3 + 3KOH \longrightarrow RNC + 3KCl + 3H_2O\) \( RNH_2 \) is a primary amine. \( CHCl_3 \) is chloroform. \( RNC \) is the isocyanide, the major product. KCl and water are by-products. Isocyanides are characterized by their strong and unpleasant odor, and their formation is a positive indication of the presence of a primary amine. Example: Let us consider the example of methanamine to explain the reaction:
Mechanism:
Summary: The major product of the Carbylamine reaction is isocyanide, making isocyanide the correct answe |