Target Exam

CUET

Subject

Chemistry

Chapter

Organic: Amines

Question:

What is the major product of Carbylamine reaction?

Options:

Cyanide

Isocyanide

Nitrile

Alkane

Correct Answer:

Isocyanide

Explanation:

The correct answer is Option (2) → Isocyanide

The major product of the Carbylamine reaction is an isocyanide.

The Carbylamine reaction (also known as the isocyanide test) is a chemical reaction used to synthesize isocyanides (also called carbylamines). This reaction involves the treatment of a primary amine (RNH₂), chloroform (CHCl₃), and a strong base (like KOH or NaOH) under heating conditions.

The general reaction is:

\(RNH_2 + CHCl_3 + 3KOH \longrightarrow RNC + 3KCl + 3H_2O\)

\( RNH_2 \) is a primary amine.

\( CHCl_3 \) is chloroform.

\( RNC \) is the isocyanide, the major product.

KCl and water are by-products.

Isocyanides are characterized by their strong and unpleasant odor, and their formation is a positive indication of the presence of a primary amine.

Example:

Let us consider the example of methanamine to explain the reaction:

Mechanism:

Summary:

The major product of the Carbylamine reaction is isocyanide, making isocyanide the correct answe