Practicing Success

Target Exam

CUET

Subject

Chemistry

Chapter

Inorganic: Coordination Compounds

Question:

Assertion: A chelating ligand must possess two or more lone pairs at such a distance that it may form suitable strain free 5 and 6 membered rings with the metal ion.
Reason: H2N- NH2 is a chelating ligand.

Options:

Assertion and reason both are correct statements and reason is correct explanation for assertion.

Assertion and reason both are correct statements but reason is not correct explanation for assertion.

Assertion is correct statement but reason is wrong statement.

Assertion is wrong statement but reason is correct statement.

Correct Answer:

Assertion is correct statement but reason is wrong statement.

Explanation:
H2NNH2 does not act as a chelating ligand. The coordinates by hydrazine lead to a three-member highly unstable strained ring and thus it does not act as a chelating agent.
 
A chelating ligand must possess two or more lone pairs at such a distance that it may form suitable strain-free rings at the metal ion.