Match List I with List II:

Choose the correct answer from the options given below:

(A)-(II), (B)-(IV), (C)-(III) D-(I)

The correct answer is option 1. (A)-(II), (B)-(IV), (C)-(III) D-(I).

Henry's law constant $K_H$ is higher for gases that are less soluble in a liquid.

• He (helium) is least soluble $\Rightarrow$ highest $K_H \Rightarrow$ matches 145 $\rightarrow$ (A)-(II)
• For the same gas, increase in temperature decreases solubility, so $K_H$ increases

$\Rightarrow K_H$ of $N_2$ at $303\text{ K} > 293\text{ K}$

$\Rightarrow 89 \rightarrow N_2 (303\text{ K}) \Rightarrow$ (B)-(IV)

$\Rightarrow 76.5 \rightarrow N_2 (293\text{ K}) \Rightarrow$ (C)-(III)

• $CO_2$ is most soluble $\Rightarrow$ lowest $K_H$ $\Rightarrow 1.67 \rightarrow$ (D)-(I)

Thus, the correct matching is: (A)-(II), (B)-(IV), (C)-(III), (D)-(I)