Elements of group- 15, 16, and 17 form compounds with hydrogen with general formula \(MH_3\), \(H_2M\), and \(HX\) (called hydrogen halides). The stability of these hydrides, along with \(M-H\) bond strength and basic nature decreases down the group. Boiling point of these hydrides mainly depends on the strength of their intermolecular forces. |
The bond angle \(HMH\) among hydrides of group 16 decreases down the group because: |
Electronegativity of the central atom decreases down the group The size of the central atom, decreases down the group Bond pair-bond pair repulsion decreases down the group with the decrease in the difference of electronegativity between hydrogen and central atom Lone pair- bond pair repulsion increases down the group |
Electronegativity of the central atom decreases down the group |
The correct answer is option 1. Electronegativity of the central atom decreases down the group. Let us look at the reason for this trend:
While lone pair-bond pair repulsion can also contribute slightly to the trend, it is not the main reason. Larger lone pairs in bigger central atoms might occupy more space and cause some repulsion with bond pairs, but their effect is much smaller compared to the dominant effect of decreasing electronegativity and increasing H-H repulsion. |