The addition of unsymmetrical reagents (like HX, X=Cl, Br, I) to unsymmetrical alkenes in presence of a peroxide occurs in such a way that the negative part of the addendum goes to the carbon atom of the double bond which carries higher number of hydrogen atoms, is given by which rule?

Markovnikov's rule Saytzeff rule Anti-Saytzeff rule Anti-Markovnikov's rule ( Kharasch effect)

Anti-Markovnikov's rule ( Kharasch effect)

The addition of unsymmetrical reagents to unsymmetrical alkene occurs in such a way that the negative part of the addendum goes to the carbon atom of the double bond which carries a higher number of hydrogen atoms is called as Anti-Markovnikov's rule or Kharasch effect.