Practicing Success
Select the incorrect statement: |
Hydrazine can act as a bidentate ligand. Oxalate is a chelating ligand. All bidentate ligands are chelating ligands. Number of chelate rings = (denticity – 1) |
Hydrazine can act as a bidentate ligand. |
The correct option is (1) Hydrazine can act as a bidentate ligand. The correct statement is: Hydrazine (H2N-NH2) as a monodentate ligand: A ligand is a molecule or ion that can donate a pair of electrons to a central metal atom or ion to form a coordination complex. Hydrazine, with two amine groups (H2N-NH2), can indeed donate a lone pair of electrons from one nitrogen atom to form a coordinate bond with a metal center, making it a monodentate ligand. Bidentate ligands and chelating ligands: A bidentate ligand is a ligand that can coordinate to a metal center by donating two lone pairs of electrons from two separate atoms in the ligand. Bidentate ligands can create a ring-like structure when coordinated to a metal center, and this phenomenon is referred to as chelation. Chelating ligands are a subset of bidentate ligands that can form such ring structures (chelates) when attached to a metal ion. Oxalate as a bidentate ligand: Oxalate is indeed a bidentate ligand. It contains two carboxylate groups (-COO-) capable of donating lone pairs of electrons to form two coordinate bonds with a metal center. When coordinated to a metal ion, oxalate forms a chelate ring. |