The rate law for a reaction between the substances A and B is given by: \[ \text{Rate} = [A]^n [B]^m \]
On doubling the concentration of A and halving the concentration of B, the ratio of the new rate to the earlier rate of the reaction will be as follows:
Doubling the concentration of A: \( [A] \rightarrow 2[A] \)
Halving the concentration of B: \( [B] \rightarrow 0.5[B] \)
Substituting these changes into the rate expression:
\[ \text{New Rate} = (2[A])^n (0.5[B])^m = 2^n [A]^n (0.5)^m [B]^m = 2^n (0.5)^m [A]^n [B]^m \]
Therefore, the ratio of the new rate to the earlier rate is:
\[ \frac{\text{New Rate}}{\text{Earlier Rate}} = \frac{2^n (0.5)^m \cdot \text{Rate}}{\text{Rate}} = 2^n (0.5)^m \]
Hence, the correct option would be (4) \( 2^{(n - m)} \), as it represents the ratio of the new rate to the earlier rate. |