Practicing Success

Target Exam

CUET

Subject

Chemistry

Chapter

Physical: Chemical Kinetics

Question:

In acidic medium the rate of reaction between BrO3- and Br- ions is given by the expression:

-\(\frac{d(BrO_3^-)}{dt}\) = k[BrO3-][Br-][H+]

Which of the following is indicated by the above expression?

Options:

Rate constant of overall reaction is 4 s-1 .

The change in pH of solution will not affect the rate.

Rate of reaction is independent.

Doubling the concentration of H+ ions will increase the reaction rate by 4 times.

Correct Answer:

Doubling the concentration of H+ ions will increase the reaction rate by 4 times.

Explanation:

As rate of reaction is given by = -\(\frac{d(BrO_3^-)}{dt}\) = k[BrO3-][Br-][H+]

it shows that rate of reaction is of 2nd order with respect to H+.

Hence, Doubling the concentration of H+ ions will increase the reaction rate by 4 times.