Practicing Success

Target Exam

CUET

Subject

Chemistry

Chapter

Physical: Chemical Kinetics

Question:

FACTORS AFFECTING RATE OF REACTION:

The rate of a chemical reaction, which measures how quickly reactants are consumed or products are formed, is influenced by several factors. Understanding these factors helps in controlling and optimizing reaction rates. Here are the key factors affecting the rate of a reaction:

  1. Nature of Reactants:The chemical nature of the reactants involved in a reaction plays a significant role. Some reactions occur more readily than others due to the inherent reactivity of the substances involved. For example, reactions between highly reactive elements or compounds tend to proceed at faster rates compared to reactions involving less reactive species.
  2. Concentration:The concentration of reactants affects the rate of a reaction. Generally, an increase in reactant concentration leads to an increase in the reaction rate. This is because a higher concentration provides more reactant particles, leading to a higher collision frequency and an increased likelihood of successful collisions.
  3. Temperature:The rate of reaction increases with the increase in temperature. In most cases, the rate of reaction becomes nearly double for 100 rise in temperature. In some cases, reactions do not take place at room temperature but take place at higher temperatures.
  4. Pressure (for gases): In the case of gaseous reactants, pressure can influence the reaction rate, particularly for reactions involving gases. Increasing the pressure of gaseous reactants can enhance the reaction rate by increasing the collision frequency between gas molecules.
  5. Surface Area: In reactions involving solid reactants, the surface area of the solid can significantly impact the reaction rate. A larger surface area provides a more exposed area for reactant particles to interact, leading to more collisions and a faster reaction rate. Therefore, finely divided or powdered forms of solids tend to react faster compared to bulky or solid pieces.
  6. Catalysts:Catalysts are substances that accelerate a reaction by providing an alternative reaction pathway with lower activation energy. They increase the rate of reaction without being consumed in the process. Catalysts can significantly enhance reaction rates and are widely used in various industrial and biological processes.
  7. Presence of Inhibitors: Inhibitors are substances that decrease the rate of a reaction. They work by interfering with the reaction mechanism, reducing the effectiveness of collisions, or inhibiting the formation of active intermediates. Inhibitors are often used to control reaction rates or to prevent unwanted reactions.

Understanding and manipulating these factors allow scientists and engineers to control and optimize reaction rates for various applications, ranging from industrial processes to pharmaceutical synthesis and energy production.

 

The rate of chemical reaction depends on the nature of reactants because

Options:

The number of bonds broken in the reactant molecules and the number of bonds formed in the product molecules changes

Some of the reactants are solids at the room temperature

Some of the reactants are coloured

All

Correct Answer:

The number of bonds broken in the reactant molecules and the number of bonds formed in the product molecules changes

Explanation:

The correct answer is option 1. The number of bonds broken in the reactant molecules and the number of bonds formed in the product molecules changes.

The rate of a chemical reaction depends on the nature of reactants primarily because: The number of bonds broken in the reactant molecules and the number of bonds formed in the product molecules changes.

This statement is correct because the rate of a chemical reaction is fundamentally determined by how easily reactant molecules can overcome the activation energy barrier to form products. This process involves the breaking of bonds in the reactants and the formation of new bonds in the products. Reactants with stronger bonds typically have higher activation energies and slower reaction rates, while reactants with weaker bonds tend to react more readily, leading to faster reaction rates.

The other options provided do not comprehensively explain why the rate of chemical reaction depends on the nature of reactants:

Some of the reactants are solids at room temperature: While the physical state (solid, liquid, gas) of reactants can affect reaction rates by influencing surface area and accessibility, it does not explain the fundamental chemical nature affecting bond strengths and reaction rates.

Some of the reactants are colored: The color of reactants does not directly relate to bond strengths or reaction rates. It may indicate the presence of certain functional groups or electronic transitions but is not a direct determinant of reaction rate.

Therefore, the primary reason why the rate of chemical reaction depends on the nature of reactants is the variation in bond strengths and the subsequent ease of bond breaking and forming during the reaction process.