Target Exam

CUET

Subject

Chemistry

Chapter

Inorganic: D and F Block Elements

Question:

Derive the electronic configuration of $Ce^{3+}$ ion by using Hund's rule.

Options:

$[Xe] 4f^1 5d^1 6s^2$

$[Xe] 4f^1$

$[Rn] 5f^2 6d^1 7s^2$

$[Rn] 5f^1$

Correct Answer:

$[Xe] 4f^1$

Explanation:

The correct answer is Option (2) → $[Xe] 4f^1$

Cerium (Ce) has atomic number 58.

Step 1: Electronic configuration of neutral Ce

$\text{Ce} : [Xe]\,4f^1\,5d^1\,6s^2$

Step 2: Formation of $\text{Ce}^{3+}$

  • Electrons are removed first from 6s, then 5d, then 4f.
  • Remove 3 electrons:
    • 2 from 6s
    • 1 from 5d

So,

$\text{Ce}^{3+} : [Xe]\,4f^1$

According to Hund’s rule, the single 4f electron remains unpaired.