Target Exam

CUET

Subject

Chemistry

Chapter

Organic: Aldehydes, Ketones and Carboxylic Acids

Question:

Aldehydes and ketones undergo

Options:

Nucleophilic substitution reaction

Nucleophilic addition reaction

Free radical reaction

Elimination reaction

Correct Answer:

Nucleophilic addition reaction

Explanation:

The correct answer is Option (2) → Nucleophilic addition reaction

  • The carbonyl group (C=O) in aldehydes and ketones is polar, with carbon being electrophilic. Therefore, they typically react with nucleophiles via addition across the double bond, not substitution.
  • Option-wise Explanation
  • 1. Nucleophilic substitution reaction This type of reaction is common in alkyl halides where a leaving group is replaced. Carbonyl compounds lack a good leaving group attached to the carbonyl carbon, so substitution is not typical.
  • 2. Nucleophilic addition reaction Nucleophiles attack the electrophilic carbon of the carbonyl group, breaking the π bond and forming an addition product. This is the characteristic reaction of aldehydes and ketones.
  • 3. Free radical reaction Free radical mechanisms usually involve alkanes or halogenation under UV light. Carbonyl compounds generally do not undergo radical reactions under normal conditions.
  • 4. Elimination reaction Elimination involves removal of small molecules (like HX or H₂O) to form double bonds. Aldehydes and ketones already have a double bond and do not typically undergo elimination as their main reaction.