Choose the alcohol which on oxidation with chromic anhydride will give a ketone. |
The correct answer is Option (3) →
Oxidation with chromic anhydride: Primary alcohol → Aldehyde → Acid Secondary alcohol → Ketone Tertiary alcohol → No oxidation Detailed Explanation Option 1: Phenol Phenols do not undergo normal oxidation to ketones with chromic anhydride. They typically form quinones or undergo ring oxidation. Option 2: Benzyl alcohol Benzyl alcohol is a primary alcohol. On oxidation with chromic anhydride, it forms benzaldehyde or further oxidizes to benzoic acid. Option 3: Cyclohexanol Cyclohexanol is a secondary alcohol. Secondary alcohols oxidize to ketones. Cyclohexanol $\rightarrow$ Cyclohexanone Option 4: Cyclohexylmethanol This is a primary alcohol and will oxidize to aldehyde and then acid, not ketone. |