Which of the following compounds comprise of a phenolic group? (A) Salicylic acid Choose the correct answer from the options given below: |
(A), (B) and (C) only (A), (B), (C) and (D) (A), (C) and (D) only (B), (C) and (D) only |
(A), (B), (C) and (D) |
The correct answer is Option (2) → (A), (B), (C) and (D) A phenolic group means an $-\text{OH}$ group directly attached to a benzene ring. The compound may also contain other functional groups $(-\text{COOH, } -\text{CHO, } -\text{CH}_3)$, but as long as an $-\text{OH}$ is bonded to the aromatic ring, it is phenolic. Explanation (option-wise) (A) Salicylic acid It is o-hydroxybenzoic acid. The $-\text{OH}$ is directly attached to the benzene ring along with a $-\text{COOH}$ group. Hence, it contains a phenolic $-\text{OH}$. (B) Salicylaldehyde This is o-hydroxybenzaldehyde. The benzene ring has both $-\text{CHO}$ and $-\text{OH}$ groups, and the $-\text{OH}$ is phenolic in nature. (C) Cresol Cresol is methyl phenol ($-\text{CH}_3$ and $-\text{OH}$ on benzene). The hydroxyl group is attached directly to the aromatic ring, so it is a phenol derivative. (D) Catechol Catechol is benzene-1,2-diol. It has two $-\text{OH}$ groups directly attached to the ring, so it definitely contains phenolic groups. |