Which of the following compounds comprise of a phenolic group?
(A) Salicylic acid
(B) Salicylaldehyde
(C) Cresol
(D) Catechol
Choose the correct answer from the options given below:
Answer & explanation
Correct answer: option 2
The correct answer is Option (2) → (A), (B), (C) and (D)
A phenolic group means an $-\text{OH}$ group directly attached to a benzene ring. The compound may also contain other functional groups $(-\text{COOH, } -\text{CHO, } -\text{CH}_3)$, but as long as an $-\text{OH}$ is bonded to the aromatic ring, it is phenolic.
Explanation (option-wise)
(A) Salicylic acid
It is o-hydroxybenzoic acid. The $-\text{OH}$ is directly attached to the benzene ring along with a $-\text{COOH}$ group. Hence, it contains a phenolic $-\text{OH}$.
(B) Salicylaldehyde
This is o-hydroxybenzaldehyde. The benzene ring has both $-\text{CHO}$ and $-\text{OH}$ groups, and the $-\text{OH}$ is phenolic in nature.
(C) Cresol
Cresol is methyl phenol ($-\text{CH}_3$ and $-\text{OH}$ on benzene). The hydroxyl group is attached directly to the aromatic ring, so it is a phenol derivative.
(D) Catechol
Catechol is benzene-1,2-diol. It has two $-\text{OH}$ groups directly attached to the ring, so it definitely contains phenolic groups.