The activation energy for a reaction at a temperature \(T K\) was found to be \(2.303RT \text{ J/mol}\). The ratio of the rate constant to Arrhenius factor is
Answer & explanation
Correct answer: option 1
The correct answer is Option (1) → \(10^{-1}\)
The Arrhenius equation relates the rate constant k to the activation energy Ea:
\( k = A\,e^{-E_a/RT} \)
Here A is the Arrhenius factor (frequency factor), and e−Ea/RT is the fraction of molecules with kinetic energy equal to or greater than Ea. So the ratio k/A is just this exponential term. Taking common logarithms:
\( \displaystyle \log\frac{k}{A} = -\frac{E_a}{2.303\,RT} \)
Substituting Ea = 2.303 RT J mol−1:
\( \displaystyle \log\frac{k}{A} = -\frac{2.303\,RT}{2.303\,RT} = -1 \)
\( \displaystyle \frac{k}{A} = 10^{-1} \)
So the ratio of the rate constant to the Arrhenius factor is 10−1.
Shortcut: Ea = 2.303 RT means Ea/RT = ln 10, so e−Ea/RT = 1/10 directly.
NCERT (2026-27 edition):
Temperature Dependence of the Rate of a Reaction – …
