Practicing Success

Target Exam

CUET

Subject

Chemistry

Chapter

Organic: Biomolecules

Question:

The weakest intermolecular forces are present in

Options:

Neoprene

Nylon 6, 6

Polyvinyl chloride

Polystyrene

Correct Answer:

Neoprene

Explanation:

The correct answer is option 1. Neoprene.

Let us delve into detail about the intermolecular forces in elastomers, particularly neoprene.

Elastomers are a class of polymers known for their rubbery and elastic properties. These materials can undergo large deformations and then return to their original shape when the applied stress is released. The unique properties of elastomers are attributed to their molecular structure and the presence of weak intermolecular forces.

Neoprene:
Neoprene is a synthetic rubber, specifically a type of polymer known as chloroprene rubber. Chloroprene is a monomer with the chemical formula \(C_4H_5Cl\), and when polymerized, it forms the polymer neoprene.

Intermolecular Forces in Neoprene:
1. Van der Waals Forces:
Neoprene is primarily held together by van der Waals forces. These forces arise from temporary fluctuations in electron distribution around atoms, leading to temporary dipoles.
The weak van der Waals forces in neoprene contribute to its flexibility and ability to stretch.

2. Polymer Chain Flexibility:
The structure of neoprene allows for significant chain slippage and movement. The polymer chains in neoprene are relatively flexible, and this flexibility is facilitated by the presence of single bonds in the polymer backbone.
The ability of the polymer chains to slide past each other contributes to the rubbery and elastic nature of elastomers like neoprene.

3. Cross-Linking:
In some cases, elastomers may contain cross-links between polymer chains. Cross-linking provides additional strength to the material and can affect its mechanical properties.
Neoprene may undergo a curing process where cross-linking occurs, enhancing its overall strength and stability.

Comparison with Other Polymers:
In contrast to neoprene, other types of polymers like thermoplastics (e.g., polyvinyl chloride - PVC) or thermosetting plastics (e.g., nylon 6,6) may exhibit stronger intermolecular forces due to their specific molecular structures and bonding patterns.

In summary, the weakest intermolecular forces in the context of the options provided are generally associated with elastomers like neoprene. The flexibility of polymer chains and the presence of van der Waals forces contribute to the unique mechanical properties of neoprene, allowing it to function as a stretchable and elastic material.