Practicing Success
Aqueous \(NaCl\) solution is electrolyzed. The product formed at the anode is: |
\(H_2\) gas \(O_2\) gas \(Na\) metal \(Cl_2\) gas |
\(Cl_2\) gas |
The correct answer is option 4. \(Cl_2\) gas. When an aqueous NaCl solution is electrolyzed, the product formed at the anode is \(Cl_2\) gas. Here's why: During electrolysis, an applied voltage forces the dissociation of \(NaCl\) molecules in the solution into \(Na^+\) and \(Cl^-\) ions. These ions migrate towards their respective electrodes: \(Na^+\) ions move towards the cathode (negative electrode), and \(Cl^-\) ions move towards the anode (positive electrode). At the cathode, water molecules \((H_2O)\) present in the solution are attracted and reduced to hydrogen gas \((H_2)\), according to the reaction: \(2H_2O + 2e^- \longrightarrow H_2 + 2OH^-\) At the anode, chloride ions \((Cl^-)\) lose electrons and are oxidized to chlorine gas \((Cl_2)\), according to the reaction: \(2Cl^- \longrightarrow Cl_2 + 2e^-\) Therefore, in an aqueous \(NaCl\) solution electrolysis, chlorine gas is produced at the anode, not hydrogen gas. |