Identify "Y" in the following reaction: |
RCOOH RCHO RCOX ROH |
RCOOH |
The correct answer is Option (1) → RCOOH Grignard reagents (R–Mg–X) are highly reactive organometallic compounds that act as strong nucleophiles. When a Grignard reagent reacts with carbon dioxide (CO₂) in dry ether, the nucleophilic carbon of the Grignard reagent attacks the electrophilic carbon of CO₂ to form a magnesium carboxylate intermediate. Reaction step: R–MgX + CO₂ → RCOO⁻MgX This intermediate is represented as X. When the reaction mixture is treated with acidic hydrolysis (H₃O⁺), the magnesium salt is protonated to produce a carboxylic acid. RCOO⁻MgX + H₃O⁺ → RCOOH Thus, the final product Y is a carboxylic acid (RCOOH). This reaction is commonly used in organic synthesis to increase the carbon chain length by one carbon atom. Option-wise Explanation Option 1: RCOOH Correct. Grignard reagent reacts with CO₂ followed by acidic hydrolysis to give a carboxylic acid. Option 2: RCHO Incorrect. Aldehydes are typically formed when Grignard reagents react with formyl derivatives, not CO₂. Option 3: RCOX Incorrect. Acyl halides are not produced in this reaction sequence. Option 4: ROH Incorrect. Alcohols are formed when Grignard reagents react with carbonyl compounds such as aldehydes or ketones, not with CO₂. |