Practicing Success

Target Exam

CUET

Subject

Chemistry

Chapter

Inorganic: D and F Block Elements

Question:

Arrange these transition metal ions, based on decreasing number of unpaired electrons.

A. \(Fe^{2+}\)

B. \(Mn^{2+}\)

C. \(Co^{2+}\)

D. \(Sc^{3+}\)

E. \(Cu^{2+}\)

Choose the correct answer from the options given below:

Options:

B > A > C > E > D

B > C > A > D > E

D > E > C > B > A

A > B > C > D > E

Correct Answer:

B > A > C > E > D

Explanation:

The correct answer is option 1. B > A > C > E > D.

The number of unpaired electrons in transition metal ions is related to their electronic configurations. Let us analyze the given ions:

A. \(Fe^{2+}\): In the ground state, the electronic configuration of neutral Fe is \([Ar] 3d^6 4s^2\). When it loses two electrons to form \(Fe^{2+}\), the 4s electrons are lost, resulting in an electronic configuration of \([Ar] 3d^6\). This has four unpaired electrons.

B. \(Mn^{2+}\): The neutral Mn has an electronic configuration of \([Ar] 3d^5 4s^2\). When it loses two electrons to form \(Mn^{2+}\), it becomes \([Ar] 3d^5\), which has five unpaired electrons.

C. \(Co^{2+}\): Neutral Co has an electronic configuration of \([Ar] 3d^7 4s^2\). When it loses two electrons to form \(Co^{2+}\), it becomes \([Ar] 3d^7\), which has three unpaired electrons.

D. \(Sc^{3+}\): Scandium (\(Sc^{3+}\)) loses three electrons from its neutral state of \([Ar] 3d^1 4s^2\), resulting in the electronic configuration of \([Ar] 3d^0\). This has no unpaired electrons.

E. \(Cu^{2+}\): The neutral Cu has an electronic configuration of \([Ar] 3d^9 4s^2\). When it loses two electrons to form \(Cu^{2+}\), it becomes \([Ar] 3d^9\), which has one unpaired electron.

So,  the correct answer is 2. B > C > A > D > E.