Target Exam

CUET

Subject

Chemistry

Chapter

Inorganic: D and F Block Elements

Question:

Arrange the following ions in increasing order of number of 3d-electrons

(A) $Cr^{2+}$
(B) $Cu^+$
(C) $Ti^{3+}$
(D) $Mn^+$

Choose the correct answer from the options given below:

Options:

(B), (A), (C), (D)

(C), (A), (D), (B)

(C), (D), (A), (B)

(D), (B), (C), (A)

Correct Answer:

(C), (A), (D), (B)

Explanation:

The correct answer is Option (2) → (C), (A), (D), (B)

1. Determine the number of $3d$-electrons for each ion

The neutral atoms have the following atomic numbers ($Z$) and ground-state electron configurations:

  • $\text{Ti} (Z=22): [\text{Ar}] 4s^2 3d^2$
  • $\text{Cr} (Z=24): [\text{Ar}] 4s^1 3d^5$ (Exception)
  • $\text{Mn} (Z=25): [\text{Ar}] 4s^2 3d^5$
  • $\text{Cu} (Z=29): [\text{Ar}] 4s^1 3d^{10}$ (Exception)

When forming ions, electrons are always removed from the outermost shell first, which is the $4s$ orbital, before the $3d$ orbital.

Ion

Neutral Atom Configuration

Ion Charge

Final Configuration

Number of 3d-electrons

(A) $\text{Cr}^{2+}$

$4s^1 3d^5$

$+2$

$4s^0 3d^4$ (Remove $1e^-$ from $4s$, $1e^-$ from $3d$)

4

(B) $\text{Cu}^{+}$

$4s^1 3d^{10}$

$+1$

$4s^0 3d^{10}$ (Remove $1e^-$ from $4s$)

10

(C) $\text{Ti}^{3+}$

$4s^2 3d^2$

$+3$

$4s^0 3d^1$ (Remove $2e^-$ from $4s$, $1e^-$ from $3d$)

1

(D) $\text{Mn}^{+}$

$4s^2 3d^5$

$+1$

$4s^1 3d^5$ (Remove $1e^-$ from $4s$)

5

2. Arrange in Increasing Order

Now, arrange the ions based on the number of $3d$-electrons in ascending order:

Number of 3d-electrons

Ion

1

$\text{Ti}^{3+}$ (C)

4

$\text{Cr}^{2+}$ (A)

5

$\text{Mn}^{+}$ (D)

10

$\text{Cu}^{+}$ (B)

The increasing order is (C), (A), (D), (B).