Read the Passage carefully and answer the questions. The carbonyl group of aldehydes and ketones is highly polar. The positively charged carbon is readily attacked by electron-rich nucleophile and the negatively charged oxygen atom is attacked by an electro-deficient electrophile. Aldehydes and ketones undergo nucleophilic addition reactions in the presence of acid or a base. The mechanism involves attack of a nucleophile on the electron deficient carbonyl carbon to form a tetrahedral intermediate. A new bond is formed between the carbon and oxygen. Protonation of the anion furnished by the reaction medium yields a neutral addition product. The addition product is same whether the reaction is catalyzed by acid or a base. For example in the presence of base aldehydes and ketones react with hydrogen cyanide to form cyanohydrin. |
What is the product formed when an aldehyde other than formaldehyde is treated with Grignard reagent? |
Carboxylic acid Primary alcohol Secondary alcohol Tertiary alcohol |
Secondary alcohol |
The correct answer is Option (3) → Secondary alcohol ** When an aldehyde (other than formaldehyde) reacts with a Grignard reagent (RMgX) followed by acid hydrolysis:
Correct answer: Secondary alcohol |