What is the formula of following coordination compound: Potassium trioxalatoaluminate(III) |
$K_3[Al(C_2O_4)_3]$ $K[Al_2(C_2O_4)_3]$ $K_3[Al_2(C_2O_4)_3]$ $K[Al(C_2O_4)_3]$ |
$K_3[Al(C_2O_4)_3]$ |
The correct answer is Option (1) → $K_3[Al(C_2O_4)_3]$ Core Concept: Oxalate ($C_2O_4^{2-}$) is a bidentate ligand with $-2$ charge. Aluminium is in $+3$ oxidation state. Stepwise Calculation: Let charge on complex $= x$ $Al^{3+} + 3(C_2O_4)^{2-}$ $= +3 + 3(-2)$ $= +3 - 6$ $= -3$ So complex ion $= [Al(C_2O_4)_3]^{3-}$. To neutralise: $3 K^+$ needed. Final formula $= K_3[Al(C_2O_4)_3]$. |