Read the passage carefully and answer the Questions. Alcohols and phenols are obtained when a hydrogen atom in aliphatic and aromatic hydrocarbons respectively, is replaced by - OH group. These compounds find wide applications in industry as well as in our daily life. You may notice that ordinary spirit is used for polishing wooden furniture which is chiefly a compound containing hydroxyl group. An alcohol contains one or more hydroxyl (OH) group(s) directly attached to carbon atom(s), of an aliphatic system ($CH_3OH$) while a phenol contains -OH group(s) directly attached to carbon atom(s) of an aromatic system ($C_6H_5OH$). Alcohols are prepared by the hydration of alkenes, fermentation of glucose, and reduction of carbonyl compounds. Alcohols produce alkenes upon dehydration whereas alkenes on acid catalyzed hydration convert into alcohols. |
The product of the following reaction is |
The correct answer is Option (3) → ** The alkene shown is propene ($CH_3-CH=CH_2$) and the reaction is acid-catalysed hydration ($H^+ / H_2O$). Complete statement: The product of the reaction is 2-propanol (isopropyl alcohol), $CH_3-CHOH-CH_3$. Reasoning: In acid-catalysed hydration, water adds to the double bond according to Markovnikov's rule. The hydrogen atom attaches to the carbon that already has more hydrogens, and the -OH group attaches to the more substituted carbon (the middle carbon in propene). This forms 2-propanol, a secondary alcohol. So, the correct structure is $CH_3-CHOH-CH_3$. |